[EN] Conférence – H. SCHWARZ – Ménage-à-Trois Single-atom Catalysis and Computational Chemistry
Conférence de Helmut SCHWARZ intitulée Ménage-à-Trois: Single-atom Catalysis, Mass Spectrometry, and Computational Chemistry
00:00:00 Introduction
00:01:14 Single-Atom Catalysts
00:02:02 Gas-phase Catalysis by Atomic and Cluster Metal Icons
00:02:28 Techniques
00:03:15 Experimental/Computational methods
00:04:19 Oxygen-atom Transport Catalysis
00:06:31 What is the metal ions’ magic?
00:08:00 Potential Energy landscape
00:08:44 The ideal Catalytic Cycle
00:09:34 Catalytic CO oxidation, poisoning, etc.
00:11:12 Which region of a molecule constitutes the Active site of a catalyst?
00:13:31 Carbon-carbon bond formation
00:14:28 Conceivable structural isomers of [MC4,H4]+ intermediates
00:15:07 Methane
00:18:01 Conversion of Methane to Methanol
00:19:36
00:20:00 Olefin Metathesis
00:20:51 Gas-phase Chemistry of [M=CH2]+
00:22:08 Gold catalyst
00:22:28 C-N coupling
00:22:37 Degussa reaction
00:26:21 Carbon-atom extrusion
00:27:44 C-C coupling
00:28:14 Activation of Methane
00:28:56 Gold Carbon cluster
00:29:22 Cluster calculation
00:30:16 H2 activation
00:32:04 High-Valent Iron Complexes
00:33:10 Alkyne
00:33:38 Reactions with alkynes
00:34:29 Nitrile-Alkyne Metathesis of [(1)FeN]2+
00:34:53 Nitrile Formation in the reaction of [(1)FeN]2+ with alkynes
00:36:03 Acknowledgements
00:36:31 Questions
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